Practice Test: Question Set - 12
1. Which of the following expressions defines the Baume gravity scale for liquids heavier than water?
- (A) (141.5/G) - 131.5
- (B) 145 - (145/G)
- (C) 200 (G-1)
- (D) (400/G) - 400
2. Ideal solution is formed, when its components have zero
- (A) Heat of mixing
- (B) Volume change
- (C) Both (a) & (b)
- (D) Neither (a) nor (b)
3. The weight fraction of methanol in an aqueous solution is 0.64. The mole fraction of methanol XM satisfies
- (A) XM < 0.5
- (B) XM = 0.5
- (C) 0.5 < XM < 0.64
- (D) XM ≥ 0.64
4. Compressibility factor of a real gas is the ratio of the actual volume to that predicted by ideal gas law. As the pressure of the gas approaches zero, the compressibility factor approaches
- (A) ∞
- (B) 0
- (C) 1
- (D) 0.24
5. The effect of pressure on the heat capacity of the gases _________ is negligible.
- (A) At pressure below one atmosphere
- (B) Below the critical temperature
- (C) Both (a) & (b)
- (D) Neither (a) nor (b)
6. CaCO3 contains ________ percent of Ca by weight.
- (A) 40
- (B) 48
- (C) 96
- (D) 12
7. The osmotic pressure of a solution increases, if its ________ is decreased.
- (A) Volume
- (B) Solute concentration
- (C) Temperature
- (D) None of these
8. One kg of saturated steam at 100°C and 1.01325 bar is contained in a rigid walled vessel. It lias a volume of 1.673 m3. It cools to 98°C; the saturation pressure is 0.943 bar ; one kg of water vapor under these conditions has a volume of 1.789 m3. The amount of water vapor condensed (in kg) is
- (A) 0.0
- (B) 0.065
- (C) 0.1
- (D) 1.0
9. A metal oxide is reduced by heating it in a stream of hydrogen. After complete reduction, it is found that 3.15 gm of the oxide has yielded 1.05 gm of the metal. It may be inferred that the
- (A) Atomic weight of the metal is 4
- (B) Equivalent weight of the metal is 4
- (C) Atomic weight of the metal is 2
- (D) Equivalent weight of the metal is 8
10. The boiling points for pure water and pure toluene are 100°C and 110.6°C respectively. Toluene and water are completely immiscible in each other. A well agitated equimolar mixture of toluene and water are prepared. If, at a total pressure of one standard atm. exerted by the vapors of water and toluene, the mole fraction of water Xw in the vapor phase satisfies
- (A) 0 < Xw < 0.5
- (B) Xw = 0.5
- (C) 0.5 < Xw < 1.0
- (D) Xw = 1.0
11. Diffusion is that property by virtue of which a perfume bottle when opened up in a room, makes the whole room fragrant with its smell. If a perfume 'X' diffuses twice as fast as another perfume 'Y'; what is the molecular weight of 'Y', if the vapor density of gas 'X' is 2? Molecular weight of gas 'X' is to be assumed to be 2.
- (A) 2
- (B) 4
- (C) 8
- (D) 16
12. Gases diffuse faster compared to liquids because of the reason that the liquid molecules
- (A) Are held together by stronger inter-molecular forces
- (B) Move faster
- (C) Have no definite shape
- (D) Are heavier
13. The number of atoms of oxygen present in 11.2 liters of ozone (O3) at N.T.P. are
- (A) 3.01 × 1022
- (B) 6.02 × 1023
- (C) 9.03 × 1024
- (D) 1.20 × 1024
14. Enthalpy of formation of NH3 is - 46 kJ/kg mole. The enthalpy change for the gaseous reaction, 2NH3 → N2 + 3H2, is equal to ________ kJ/kg. mole.
- (A) 46
- (B) 92
- (C) -23
- (D) -92
15. N2 content in a urea sample was found to be only 42%. What is the actual urea content of the sample? (Molecular weight of urea = 60)
- (A) 80%
- (B) 90%
- (C) 95%
- (D) 98%
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