Practice Test: Question Set - 20
1. The extensive properties are
- (A) Volume, mass and number of moles
- (B) Free energy, entropy and enthalpy
- (C) Both (a) and (b)
- (D) None of these
2. For organic compounds, group contribution method can be used for the estimation of
- (A) Critical properties
- (B) Specific gravity
- (C) Specific volume
- (D) Thermal conductivity
3. In an ideal gas mixture, fugacity of a species is equal to its
- (A) Vapor pressure
- (B) Partial pressure
- (C) Chemical potential
- (D) None of these
4. __________ increases with increase in pressure.
- (A) The melting point of wax
- (B) The boiling point of a liquid
- (C) Both (a) and (b)
- (D) Neither (a) nor (b)
5. A large iceberg melts at the base, but not at the top, because of the reason that
- (A) Ice at the base contains impurities which lowers its melting point
- (B) Due to the high pressure at the base, its melting point reduces
- (C) The iceberg remains in a warmer condition at the base
- (D) All (a), (b) and (c)
6. The enthalpy change when ammonia gas is dissolved in water is called the heat of
- (A) Solution
- (B) Formation
- (C) Dilution
- (D) Combustion
7. At normal boiling point, molar entropy of vaporization is __________ Joule/K°.mole.
- (A) 72
- (B) 92
- (C) 142
- (D) 192
8. Trouton's ratio is given by (where λb, = molal heat of vaporization of a substance at its normal boiling point, kcal/kmol Tb = normal boiling point, °K)
- (A) λb/Tb
- (B) Tb/λb
- (C) √(λb/Tb)
- (D) √(Tb/λb)
9. The theoretical minimum work required to separate one mole of a liquid mixture at 1 atm, containing 50 mole % each of n- heptane and n- octane into pure compounds each at 1 atm is
- (A) -2 RT ln 0.5
- (B) -RT ln 0.5
- (C) 0.5 RT
- (D) 2 RT
10. Joule-Thomson co-efficient depends on the
- (A) Pressure
- (B) Temperature
- (C) Both (a) & (b)
- (D) Neither (a) nor (b)
11. __________ Equation predicts the activity co-efficient from experimental data.
- (A) Lewis-Randall
- (B) Margules
- (C) Van Laar
- (D) Both (b) & (c)
12. Which of the following processes cannot be made reversible even under ideal condition of operation?
- (A) Free expansion of a gas
- (B) Compression of air in a compressor
- (C) Expansion of steam in a turbine
- (D) All (a), (b) & (c)
13. Charles' law for gases states that
- (A) V/T = Constant
- (B) V ∝ 1/T
- (C) V ∝ 1/P
- (D) PV/T = Constant
14. "Law of corresponding states" says that
- (A) Two different gases behave similarly, if their reduced properties (i.e.
P, V and T) are same
- (B) The surface of separation (i. e. the meniscus)
between liquid and vapor phase disappears at the critical temperature
- (C) No gas can be liquefied above the critical temperature, howsoever
high the pressure may be
- (D) The molar heat of energy of gas at constant volume should be nearly
constant (about 3 calories)
15. At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by (where, μ = standard chemical potential at unit fugacity (f° = 1 atm.) and the gas behaves ideally.)
- (A) μ° + RT ln f
- (B) μ°+ R ln f
- (C) μ° + T ln f
- (D) μ° + R/T ln f
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