Practice Test: Question Set - 10
1. For an exothermic reaction
- (A) Only enthalpy change (ΔH) is negative
- (B) Only internal energy change (ΔE) is negative
- (C) Both ΔH and ΔE are negative
- (D) Enthalpy change is zero
2. Which of the following is not a reversible process?
- (A) Expansion of an ideal gas against constant pressure
- (B) Atmospheric pressure vaporization of water at 100°C
- (C) Solution of NaCl in water at 50°C
- (D) None of these
3. For spontaneous changes in an isolated system (S = entropy)
- (A) ds = 0
- (B) ds < 0
- (C) ds > 0
- (D) ds = Constant
4. With increase in reduced temperature, the fugacity co-efficient of a gas at constant reduced pressure
- (A) Increases
- (B) Decreases
- (C) Remain same
- (D) Decreases linearly
5. The absolute entropy for all crystalline substances at absolute zero temperature is
- (A) Zero
- (B) Negative
- (C) More than zero
- (D) Indeterminate
6. The expression for entropy change given by, ΔS = nR ln (V2/V1) + nCv ln (T2/T1) is valid for
- (A) Reversible isothermal volume change
- (B) Heating of a substance
- (C) Cooling of a substance
- (D) Simultaneous heating and expansion of an ideal gas
7. In the equation, PVn = constant, if the value of n = 1, then it represents a reversible __________ process.
- (A) Isothermal
- (B) Isobaric
- (C) Polytropic
- (D) Adiabatic
8. Critical temperature is defined as the temperature above which a gas will
- (A) Not liquify (barring exceptions)
- (B) Immediately liquify
- (C) Never liquify however high the pressure may be
- (D) None of these
9. The second law of thermodynamics states that
- (A) The energy change of a system undergoing any
reversible process is zero
- (B) It is not possible to transfer heat from a lower temperature to a
higher temperature
- (C) The total energy of system and surrounding remains the same
- (D) None of the above
10. For equilibrium process (i.e. reversible) in an isolated system
- (A) ds = 0
- (B) ds < 0
- (C) ds > 0
- (D) ds = Constant
11. A gas has a volume of 27.3 c.c. at 0°C. Its volume at 10°C (if pressure remains unchanged) will be __________ c.c.
- (A) 2.73
- (B) 28.3
- (C) 273
- (D) 283
12. First law of thermodynamics deals with the
- (A) Direction of energy transfer
- (B) Reversible processes only
- (C) Irreversible processes only
- (D) None of these
13. The energy of activation of exothermic reaction is
- (A) Zero
- (B) Negative
- (C) Very large compared to that for endothermic reaction
- (D) Not possible to predict
14. The first law of thermodynamics is a statement of conservation of
- (A) Heat
- (B) Momentum
- (C) Energy
- (D) Work
15. Which of the following is not a common refrigerant?
- (A) Freon-12
- (B) Ethylene
- (C) Ammonia
- (D) Carbon dioxide
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