Practice Test: Question Set - 20
1. A catalyst is said to be a negative catalyst, if it
- (A) Retards the rate of reaction
- (B) Reduces the value of equilibrium constant
- (C) Does not initiate the reaction
- (D) All (a), (b) and (c)
2. For multiple reactions, the flow pattern within the vessel affects the
- (A) Size requirement
- (B) Distribution of reaction products
- (C) Both (a) and (b)
- (D) Neither (a) nor (b)
3. Pick out the wrong statement.
- (A) The vessel dispersion number (D/UL) for plug flow and
mixed flow approaches zero and infinity respectively
- (B) Space time in a flow reactor is a measure of its capacity and is
equal to the residence time when the density of reaction mixture is constant
- (C) Mixed reactor is always smaller than the plug
flow reactor for all positive reaction orders for a particular duty
- (D) In an ideal tubular flow reactor, mixing takes
place in radial direction and there is no mixing in longitudinal direction
4. The irreversible reaction is a special case of reversible reaction, if the
- (A) Equilibrium constant is 1
- (B) Conversion of the reactant at equilibrium condition is zero
- (C) Reactant concentration at equilibrium condition is zero
- (D) All (a), (b) and (c)
5. Rate of a chemical reaction is not influenced by the
- (A) Catalyst
- (B) Temperature
- (C) Reactants concentration
- (D) Number of molecules of reactants taking part in
a reaction
6. If Thiele modulus is __________, then the pore diffusion resistance in a catalyst may be considered as negligible.
- (A) 0
- (B) ∞
- (C) < 0.5
- (D) > 0.5
7. __________ explains the mechanism of catalysis.
- (A) Activated complex theory
- (B) Collision theory
- (C) Thermodynamics
- (D) None of these
8. Which of the following factors control the design of a fluid-solid reactor?
- (A) Reaction kinetics for single particle
- (B) Size distribution of solids being treated
- (C) Flow patterns of solids and fluid in the reactor
- (D) All (a), (b) and (c)
9. For an autocatalytic reactor, the suitable reactor set up is
- (A) P.F. reactors in series
- (B) CSTR in series
- (C) CSTR followed by P.F. reactor
- (D) P.F. reactor followed by CSTR
10. Pick out the wrong statement.
- (A) Exit age description function (E) and internal age
distribution function (I) are related as, E = -(dI/dθ)
- (B) Chmisorption studies are useful in the determination of catalyst
surface area and pore size distribution
- (C) A higher temperature favors the reaction of higher activation energy
- (D) A catalyst increases the potential energy barrier over which the
reactants must pass to form products
11. A reactor is generally termed as an autoclave, when it is a
- (A) High pressure batch reactor
- (B) Atmospheric pressure tank reactor
- (C) High pressure tubular reactor
- (D) Atmospheric pressure CSTR
12. If n = overall order of a chemical reaction. a = initial concentration of reactant. t = time required to complete a definite fraction of the reaction. Then pick out the correct relationship.
- (A) t ∝ 1/an
- (B) t ∝ 1/an - 1
- (C) t ∝ 1/an + 1
- (D) t ∝ an
13. A CSTR is to be designed in which an exothermic liquid phase first order reaction of the type, A → R, is taking place. The reactor is to be provided with a jacket in which coolant is flowing. Following data is given: CA0= 5 kmole/m3; XA = 0.5; Feed temperature = reactor temperature = 40°C. Rate constant at 40°C = 1 min-1; (ΔH) = - 40kJ/mole; ρ = 1000kg/m3 CP = 4 J/gm.°C ; q = 10-3 m3/min (ρ and CP are same for the reactant and product streams). The amount of heat to be removed is:
- (A) 2/3 kW
- (B) 1 kW
- (C) 5/3 kW
- (D) 4 kW
14. A space time of 3 hours for a flow reactor means that
- (A) The time required to process one reactor volume of feed (measured at
specified conditions) is 3 hours
- (B) Three reactor volumes of feed can be processed every hour
- (C) It takes three hours to dump the entire volume of the reactor with
feed
- (D) Conversion is cent per cent after three hours
15. For a reaction of the type of bellow given figure, the rate of reaction (- rx) is given by
- (A) (K1 + K1) CX
- (B) (K1 + K2+K3) CX
- (C) K1CV - K2CX
- (D) (K1 - K2) CX
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