Practice Test: Question Set - 31
1. The role of a catalyst in a chemical reaction is to change the
- (A) Equilibrium constant
- (B) Activation energy
- (C) Final products
- (D) Heat of reaction
2. For a gaseous phase reaction, rate of reaction is equal to K. CA . CB. If the volume of the reactor is suddenly reduced to 1/4th of its initial volume, then the rate of reaction compared to the original rate will be __________ times.
- (A) 8
- (B) 16
- (C) 1/8
- (D) 1/16
3. The reactions of high molecularity are rare, because
- (A) Of very large activation energy of many bodies
- (B) Of low probability of many body collisions
- (C) Many body collisions are not favored
energetically
- (D) Of requirement of very large concentration for such reactions
4. The effect of increasing pressure on the gaseous equilibrium of the reaction 2X+3Y ⇌ 3X+2Y indicates that
- (A) Pressure has no effect
- (B) Backward reaction is favored
- (C) Forward reaction is favored
- (D) None of these
5. Holding time for flow reactors is __________ the space time, for constant fluid density
- (A) Double
- (B) Triple
- (C) Equal to
- (D) None of these
6. Signal normally used to study non-ideal flow by stimulus response technique is __________ input.
- (A) Pulse
- (B) Step
- (C) Both (a) & (b)
- (D) Neither (a) nor (b)
7. Design of heterogamous catalytic reactor involves consideration of __________ steps.
- (A) Only chemical
- (B) Only physical
- (C) Both (a) & (b)
- (D) Neither (a) nor (b)
8. A high space velocity means that a given
- (A) Reaction can be accomplished with small reactor
- (B) Conversion can be obtained with a high feed rate
- (C) Both (a) and (b)
- (D) None of these
9. Pick the WRONG design guideline for a reactor in which the reactions, A → R (desired) and A → S (undesired) are to take place. The ratio of the reaction rates is rR/rS = (k1/k2). CAa-b
- (A) Use high pressure and eliminate inerts, when a > b
- (B) Avoid recycle, when a > b
- (C) Use batch reactor or plug flow reactor, when a > b
- (D) Use CSTR with a high conversion, when a > b
10. At a given value of E/R (ratio of activation energy and gas constant), the ratio of the rate constants at 500°K and 400°K is 2, if Arrhenius law is used. What will be this ratio, if transition state theory is used with the same value of ‘E/R’?
- (A) 1.6
- (B) 2
- (C) 2.24
- (D) 2.5
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