Practice Test: Question Set - 11
1. The irreversible reaction, X → Y, is the special case of the reversible reaction, X ⇌ Y, in which the
- (A) Equilibrium constant is infinite
- (B) Fractional conversion of 'A' at equilibrium is
unity
- (C) Concentration of 'A' at equilibrium is zero
- (D) All (a), (b) and (c)
2. The catalyst in a first order chemical reaction changes the
- (A) Equilibrium constant
- (B) Activation energy
- (C) Heat of formation of the product
- (D) Heat of reaction
3. Pick out the correct statement.
- (A) A chemical reaction accompanied by absorption of
heat is called an exothermic reaction
- (B) A chemical reaction accompanied by evolution of
heat is called an endothermic reaction
- (C) The rate constant for a first order reaction
does not change on changing the concentration units
- (D) Chemical equilibrium state is dynamic in nature
4. In chamber process of sulphuric acid manufacture in industry, the gas phase oxidation of SO2 to SO3 is accomplished by a __________ reaction.
- (A) Non-catalytic homogeneous
- (B) Non-catalytic heterogeneous
- (C) Catalytic homogenous
- (D) Catalytic heterogeneous
5. For identical flow rate and feed composition, X plug flow reactors (PER) in series with a total volume V gives the same conversion as single
- (A) CSTR of volume V
- (B) PFR of volume V
- (C) CSTR of volume V/X
- (D) PFR of volume V/X
6. For a tubular flow reactor with uniform concentration and temperature, the independent variable is
- (A) Time
- (B) Length
- (C) Diameter
- (D) None of these
7. In case of unimolecular type elementary reaction as shown in the bellow figure, plug flow reactor as compared to mixed reactor is:
- (A) More
- (B) Same
- (C) Less
- (D) Unpredictable
8. Differential method for analyzing the kinetic data is used
- (A) For testing complicated mechanisms
- (B) When the data are scattered
- (C) When rate expressions are very simple
- (D) None of these
9. Fractional conversion __________ for an exothermic reversible chemical reaction, when the temperature is maximum.
- (A) Increases
- (B) Remains unchanged
- (C) Decreases
- (D) Unpredictable from the data
10. Which of the following is not endothermic in nature?
- (A) Combustion of sulphur
- (B) Gasification of carbon
- (C) Thermal cracking of fuel oil
- (D) Steam reforming of naphtha
11. Overall rate of reaction in a heterogeneous catalytic reaction depends upon the mass and energy transfer from the fluid to solid surface and its rate of reaction is usually __________ the concentration of catalyst, if it does not entail a chain mechanism.
- (A) Proportional to
- (B) Independent of
- (C) Inversely proportional to
- (D) Proportional to the square of
12. The reaction in which one of the products of reaction acts as a catalyst is called a/an __________ reaction.
- (A) Biochemical
- (B) Photochemical
- (C) Catalytic
- (D) Autocatalytic
13. The use of space time is preferred over the mean residence time in the design of a/an
- (A) Batch reactor
- (B) Ideal tubular-flow reactor
- (C) Slurry reactor
- (D) CSTR
14. Oil is hydrogenated using nickel catalyst in a __________ reactor.
- (A) Batch
- (B) Slurry
- (C) Fluidized bed
- (D) Fixed bed
15. A first order reaction A → B occurs in an isothermal porous catalyst pellet of spherical shape. If the concentration of A at the center of the pellet is much less than at the external surface, the process is limited by
- (A) Diffusion within the pellet
- (B) Reaction
- (C) External mass transfer
- (D) None of the above
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